ISO 23874:2006 describes the performance requirements for analysis of treated natural gas of transmission or pipeline quality in sufficient detail so that the hydrocarbon dewpoint temperature can be calculated using an appropriate equation of state. ISO 23874:2006 can be applied to gases that have maximum dewpoint temperatures (cricondentherms) between 0 °C and - 50 °C. The pressures at which these maximum dewpoint temperatures are calculated are in the range 2 MPa (20 bar) to 5 MPa (50 bar). The procedure given in ISO 23874:2006 covers the measurement of hydrocarbons in the range C5 to C12. n-Pentane, which is quantitatively measured using ISO 6974 (all parts), is used as a bridge component and all C6 and higher hydrocarbons are measured relative to n-pentane. Major components are measured using ISO 6974 (all parts) and the ranges of components that can be measured are as defined in ISO 6974-1.
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Sisällysluettelo
Foreword
1 Scope
2 Normative references
3 Principle
4 Materials
5 Apparatus
6 Performance requirements
6.1 Major components
6.2 Higher hydrocarbons
7 Sampling
8 Analytical procedure
8.1 Major components
8.2 Higher hydrocarbons
9 Methods of test
9.1 Introduction of a typical sample of natural gas
9.2 Calculation of the composition
9.3 Calculation of fraction quantities and properties
10 Uncertainty in composition
11 Calculation of dewpoint temperature
12 Analytical uncertainty contribution to dewpoint temperature
Annex A Typical analytical conditions for C5 to C12 analysis (informative)
Annex B Validation of fraction data (informative)
Annex C Precision of area ratio (informative)
Annex D Recommendations on sample calibration gas introduction (informative)
Annex E Calculation of fraction quantities, boiling points and component uncertainties (informative)
ISO 10715:1997 Natural gas -- Sampling guidelines
ISO 6974-1:2012 Natural gas -- Determination of composition and associated uncertainty by gas chromatography -- Part 1: General guidelines and calculation of composition
ISO 6974-2:2012 Natural gas -- Determination of composition and associated uncertainty by gas chromatography -- Part 2: Uncertainty calculations
ISO 10715:1997 Natural gas -- Sampling guidelines
ISO 6974-1:2012 Natural gas -- Determination of composition and associated uncertainty by gas chromatography -- Part 1: General guidelines and calculation of composition
ISO 6974-2:2012 Natural gas -- Determination of composition and associated uncertainty by gas chromatography -- Part 2: Uncertainty calculations
ISO 6974-3:2000 Natural gas -- Determination of composition with defined uncertainty by gas chromatography -- Part 3: Determination of hydrogen, helium, oxygen, nitrogen, carbon dioxide and hydrocarbons up to C8 using two packed columns
ISO 6974-4:2000 Natural gas -- Determination of composition with defined uncertainty by gas chromatography -- Part 4: Determination of nitrogen, carbon dioxide and C1 to C5 and C6+ hydrocarbons for a laboratory and on-line measuring system using two columns
ISO 6974-5:2014 Natural gas -- Determination of composition and associated uncertainty by gas chromatography -- Part 5: Isothermal method for nitrogen, carbon dioxide, C1 to C5 hydrocarbons and C6+ hydrocarbons
ISO 6974-6:2002 Natural gas -- Determination of composition with defined uncertainty by gas chromatography -- Part 6: Determination of hydrogen, helium, oxygen, nitrogen, carbon dioxide and C1 to C8 hydrocarbons using three capillary columns
ISO 6975:1997 Natural gas -- Extended analysis -- Gas-chromatographic method