This part of ISO 20765 specifies a method of calculation for the volumetric and caloric properties of natural gases, natural gases containing synthetic admixture and similar mixtures, at conditions where the mixture can exist only as a gas. The method is applicable to pipeline-quality gases within the ranges of pressure and temperature at which transmission and distribution operations normally take place. For volumetric properties (compression factor and density), the uncertainty of calculation is about ± 0,1 % (95 % confidence interval). For caloric properties (for example enthalpy, heat capacity, Joule-Thomson coefficient, speed of sound), the uncertainty of calculation is usually greater.
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Sisällysluettelo
Foreword
Introduction
1 Scope
2 Normative references
3 Terms and definitions
4 Thermodynamic basis of the method
4.1 Principle
4.2 The fundamental equation of Helmholtz free energy
4.3 Thermodynamic properties derived from the Helmholtz free energy
5 Method of calculation
5.1 Input variables
5.2 Conversion from pressure to reduced density
5.3 Implementation
6 Ranges of application
6.1 Pressure and temperature
6.2 Pipeline quality gas
7 Uncertainty
7.1 Uncertainty for pipeline quality gas
7.2 Impact of uncertainties of input variables
8 Reporting of results
Annex A Symbols and units (normative)
Annex B The Helmholtz free energy of the ideal gas (normative)
Annex C The equation for the Helmholtz free energy (normative)
Annex D Detailed documentation for the equation of state (normative)
Annex E Assignment of trace components (informative)
Annex F Implementation of the method (informative)
ISO 12213-2:2006 Natural gas -- Calculation of compression factor -- Part 2: Calculation using molar-composition analysis
ISO 14532:2014 Natural gas -- Vocabulary
ISO 31-3:1992 Quantities and units -- Part 3: Mechanics
ISO 12213-2:2006 Natural gas -- Calculation of compression factor -- Part 2: Calculation using molar-composition analysis
ISO 14532:2014 Natural gas -- Vocabulary
ISO 31-3:1992 Quantities and units -- Part 3: Mechanics
ISO 31-4:1992 Quantities and units -- Part 4: Heat
ISO 7504:2015 Gas analysis -- Vocabulary