Water quality. Determination of dalapon, trichloroacetic acid and selected haloacetic acids. Method using gas chromatography (GC-ECD and/or GC-MS detection) after liquid-liquid extraction and derivatization (ISO 23631:2006)
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ISO 23631:2006 specifies a method for the determination of dalapon, trichloroacetic acid (TCA) and selected haloacetic acids in ground water and drinking water by gas chromatography (GC-ECD and/or GC-MS detection) after liquid-liquid-extraction and derivatization using diazomethane. Depending on the matrix, the method is applicable to a concentration range from 0,5 to 10 micrograms per litre. The validated reporting limit of TCA and dalapon is about 0,05 micrograms per litre. Detection by electron-capture detector (ECD) in general leads to lower detection limits. Detection by mass spectrometry (MS) allows analyte identification.
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Sisällysluettelo
Foreword
Introduction
1 Scope
2 Normative references
3 Principle
4 Interferences
4.1 Interferences with the extraction procedure
4.2 Interferences with the gas chromatography and mass spectrometry procedure
5 Reagents
6 Apparatus
7 Sampling and sample pre-treatment
8 Procedure
8.1 Sample preparation and extraction
8.2 Concentration and derivatization
8.3 Gas chromatography analysis of individual compounds
8.4 Blank value measurements
9 Calibration
9.1 General requirements
9.2 Calibration of the GC step not covering the total procedure
9.3 Calibration with external standard covering the total procedure
9.4 Calibration with internal standard covering the total procedure
9.5 Determination of procedural recovery values
10 Calculation
10.1 Calculation of single results by calibration with external standard covering the total procedure
10.2 Calculation of single results by calibration with internal standard covering the total procedure
11 Expression of results
12 Test report
Annex A Examples of gas chromatograms (informative)
Annex B Mass spectra of methylated dalapon and haloacetic acids (informative)
ISO 3696:1987 Water for analytical laboratory use -- Specification and test methods
ISO 5667-1:1980 Water quality -- Sampling -- Part 1: Guidance on the design of sampling programmes
ISO 5667-2:1991 Water quality -- Sampling -- Part 2: Guidance on sampling techniques
ISO 3696:1987 Water for analytical laboratory use -- Specification and test methods
ISO 5667-1:1980 Water quality -- Sampling -- Part 1: Guidance on the design of sampling programmes
ISO 5667-2:1991 Water quality -- Sampling -- Part 2: Guidance on sampling techniques
ISO 5667-3:2003 Water quality -- Sampling -- Part 3: Guidance on the preservation and handling of water samples