Water quality. Determination of total cyanide and free cyanide using flow analysis (FIA and CFA). Part 1: Method using flow injection analysis (FIA) (ISO 14403-1:2012)
Tuote ladattavissa hetiToimitusaika on noin 1 - 2 työpäivääToimitusaika on 3 - 5 työpäivää.
ISO 14403-1:2012 specifies methods for the determination of cyanide in various types of water (such as ground, drinking, surface, leachate, and waste water) with cyanide concentrations from 2 µg/l to 500 µg/l expressed as cyanide ions in the undiluted sample. The range of application can be changed by varying the operation conditions, e.g. by diluting the original sample or using a different injection volume. In ISO 14403-1:2012, a suitable mass concentration range from 20 µg/l to 200 µg/l is described. Seawater can be analysed with possible changes in sensitivity and adaptation of the reagent and calibration solutions to the salinity of the samples.
Tämän julkaisun valmistelusta Suomessa vastaa Suomen ympäristökeskus, puh. 040 724 8795.
Sisällysluettelo
Foreword
Introduction
1 Scope
2 Normative references
3 Terms and definitions
4 Interferences
4.1 Interferences by oxidizing agents
4.2 Interferences by sulfide, sulfite, nitrite, and carbonyl compounds
4.3 Other interferences
5 Principle
5.1 Determination of total cyanide
5.2 Determination of free cyanide
6 Reagents
7 Apparatus
8 Sampling and sample preparation
9 Procedure
9.1 Flow system set-up
9.2 Reagent blank measurement
9.3 Checking the suitability of the flow system
9.4 Calibration
9.5 Sample measurement
10 Calculation
11 Expression of results
12 Test report
Annex A Examples of flow systems (informative)
Annex B Determination of the real cyanide concentration in the potassium cyanide solution (6.18.1) (normative)
ISO 3696:1987 Water for analytical laboratory use -- Specification and test methods
ISO 5667-3:2003 Water quality -- Sampling -- Part 3: Guidance on the preservation and handling of water samples
ISO 8466-1:1990 Water quality -- Calibration and evaluation of analytical methods and estimation of performance characteristics -- Part 1: Statistical evaluation of the linear calibration function
ISO 3696:1987 Water for analytical laboratory use -- Specification and test methods
ISO 5667-3:2003 Water quality -- Sampling -- Part 3: Guidance on the preservation and handling of water samples
ISO 8466-1:1990 Water quality -- Calibration and evaluation of analytical methods and estimation of performance characteristics -- Part 1: Statistical evaluation of the linear calibration function
ISO 8466-2:2001 Water quality -- Calibration and evaluation of analytical methods and estimation of performance characteristics -- Part 2: Calibration strategy for non-linear second-order calibration functions