This document specifies a method for determining alkylphenols (nonylphenol and octylphenol) and alkylphenol ethoxylates (nonylphenol ethoxylate and octylphenol ethoxylate) in leather and process auxiliaries. The analysis is based on high-performance liquid chromatography (HPLC) or gas chromatography-mass spectrometry (GC-MS). The analysis of the alkylphenol ethoxylate is made by cleaving the alkylphenol ethoxylate and measuring the released alkylphenol. NOTE ISO 18218-1 and this document use different solvents for the extraction of the ethoxylated alkylphenols from leather. Consequently, the two analytical methods are expected to give similar trends but not necessarily the same absolute result for the ethoxylated alkylphenol content in leather.
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Foreword
Introduction
1 Scope
2 Normative references
3 Terms and definitions
4 Principle
5 Apparatus and materials
6 Chemicals
7 Sampling and sample preparation
7.1 Preparation of leather samples
7.2 Preparation of leather process auxiliary samples
7.3 Blank determination
7.4 Determination of OP and NP
7.5 Determination of OPEO and NPEO
7.6 Chromatographic analysis
7.7 Evaluation
8 Calibration
8.1 Calibration for OP and NP
8.2 Calibration for OPEO and NPEO
9 Calculation
9.1 Calculation of OP and NP
9.2 Calculation of OPEO and NPEO
10 Test report
Annex A Preparation of aluminium triiodide (normative)
Annex B Example of HPLC chromatograms (informative)
Annex C Example of GC-MS chromatograms (informative)
ISO 2418:2017 Leather -- Chemical, physical and mechanical and fastness tests -- Sampling location
ISO 3696:1987 Water for analytical laboratory use -- Specification and test methods
ISO 4044:2017 Leather -- Chemical tests -- Preparation of chemical test samples
ISO 2418:2017 Leather -- Chemical, physical and mechanical and fastness tests -- Sampling location
ISO 3696:1987 Water for analytical laboratory use -- Specification and test methods
ISO 4044:2017 Leather -- Chemical tests -- Preparation of chemical test samples